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疏水缔合水溶性聚合物合成新方法

齐从丽，钟敬敏，焦瑞琴
(中国石化西南分公司工程技术研究院，四川 德阳 618000)
摘　要 综述了疏水缔合型水溶性聚合物及其合成方法，包括共聚合法(非均相、均相、胶束、反相微乳液、无皂乳液以及阴离子聚合)和大分子反应法。同时，介绍了合成过程中提高油溶性单体和水溶性单体混溶性的方法，简述了合成方法对聚合物结构的影响。
关键词 疏水缔合聚合物 合成 非均相 均相 胶束 反相微乳液 无皂乳液 阴离子聚合 油溶性单体 水溶性单体
 



The New Methods of Synthesis of Hydrophobically
Associating Water-soluble Polymers

Qi Congli，Zhong Jingmin，Jiao Ruiqin
(Engineering Technology Institute，SINOPEC SouthWest Company，Sichuan Deyang 618000)
[Abstract] This paper reviews various methods of synthesis of hydrophobically associating water-soluble polymers，including copolymerization of acrylamide with hydrophobic monomers(heterogeneous process，homogeneous process，micellar copolymerization，inverse microemulsion process，emulsion process without emulsifying agents and anionic copolymerization)and macromolecular reactions.Meanwhile，it introduces the methods which are to increase the miscibility of oil-soluble and water-soluble monomers during synthetic process.And it illuminates the effection of the methods of synthesis on the structures of polymers.
[Keywords] hydrophobically associating water-soluble polymers；synthesis；heterogeneous process；homogeneous process；micellar；inverse microemulsion；emulsion without emulsifying agents；anionic copolymerization；oil-soluble monomers；water-soluble monomers



作者简介：齐从丽，工程师，2005年毕业于西南石油学院研究生院应用化学专业，现就职于中国石化西南分公司技术研究院，主要从事钻井液方面的研究工作。